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(S)-(+)-2,2'-双(二-4-甲基苯基膦)-1,1'-联萘
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3029940 | 100mg | 630 | |||
| 3029940 | 0.5g | 1920 | |||
| 3029940 | 2g | 4900 | |||
| 3029940 | 10g | 18440 |
产品别名
100165-88-6
(S)-(+)-2,2'-双(二-4-甲基苯基膦)-1,1'-联萘
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
(S)-Tol-BINAP
基本信息
| 应用 | (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is chiral ligand widely used in asymmetric synthesis. It also used as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides. BINAP is used in organic synthesis for enantioselective transformations catalyzed by its complexes of ruthenium, rhodium, and palladium |
| 备注 | Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers. |
| MDL | MFCD00269856 |
| 分子式 | C48H40P2 |
| 分子量 | 678.79 |
| 熔点 | 255-257° |
| 灵敏度 | Ambient temperatures. |
| 形态 | Powder |
| 溶解性 | Insoluble in water. |
| 包装组 | III |
| 危险类别 | 36/37/38 Irritating to eyes, respiratory system and skin. |
安全信息
| 危险等级 | 6.1 |
| 安全等级 | 26-37 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| TSCA | 否 |
GHS危害和防范说明
| GHS符号 |  |
| Hazard Statements | H315-H319-H335 Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
| Precautionary Statements | P261-P280a-P305+P351+P338-P304+P340-P405-P501a Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |
