氯化铋(III),无水

Catalysts for organic reactions, preparation of Bi salts.Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

Hygroscopic. Incompatible with strong oxidizing agents.

MFCD00003461

232-123-2

BiCl₃

315.34

230-232°

ca 430° subl.

4.75

Hygroscopic. Store under Nitrogen. Ambient temperatures.

Powder

Soluble in HCl, HNO{3}, acetone, ethyl acetate. Insoluble in alcohol. Decomposed by water to BiOCl.Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.

14,1262

34
Causes burns.

3-20-26-36/37/39-45-60
Keep in a cool place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

EB2690000

 

是

 

H303-H314-H318
May be harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.