1,5-环辛二烯(吡啶)(三环己基磷)铱(I)六氟磷酸盐

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

Moisture sensitive. Incompatible with oxidizing agents.

MFCD00075097

C₃₁H₅₀F₆IrNP₂

804.89

175° dec.

Moisture Sensitive. Ambient temperatures.

Orange crystalline powder

Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.

36/38
Irritating to eyes and skin.

26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

否

 

H315-H319
Causes skin irritation.Causes serious eye irritation.

P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.