(±)-反式-1,2-环己二胺

(^+)-trans-1,2-Diaminocyclohexane is employed in the synthesis of macrocyclic [3+3] hexa Schiff base. It also plays an important role in the preparation of multidentate ligands, chiral auxiliaries and chiral stationary phases. Further, it is used to prepare [2+2] macrocyclization by reacting with aliphatic dialdehydes. In addition to this, it acts as a chiral ligand, which finds application in asymmetric catalysis.

Incompatible with strong oxidizing agents and strong acids.

MFCD00063747

C₆H₁₄N₂

114.19

14-15°

89-90°/14mm

68°(154°F)

0.951

1.4890

Keep Cold. Air Sensitive. May form a Precipitate. Store under Nitrogen.

Liquid

Miscible with water.

3193807

II

34
Causes burns.

8

20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

 

是

 

H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

P262-P280-P305+P351+P338-P309-P310
Do not get in eyes, on skin, or on clothing.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.