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1,3-二(2,4,6-三甲基苯基)氯化咪唑
1,3-Dimesitylimidazolium Chloride
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3043326 | 1g | 1490 | |||
| 3043326 | 5g | 3510 |
产品别名
141556-45-8
1,3-二(2,4,6-三甲基苯基)氯化咪唑
1,3-Dimesitylimidazolium Chloride
1,3-Bis(2,4,6-trimethylphenyl)imidazolium Chloride
基本信息
| 应用 | Used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1,3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides. |
| 备注 | Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. |
| MDL | MFCD02684541 |
| 分子式 | C21H25ClN2 |
| 分子量 | 340.89 |
| 熔点 | >300° |
| 灵敏度 | Ambient temperatures. |
| 形态 | Solid |
| 溶解性 | Slightly soluble in water. |
| 危险类别 | 36/37/38 Irritating to eyes, respiratory system and skin. |
安全信息
| 安全等级 | 26-37 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| TSCA | 否 |
GHS危害和防范说明
| GHS符号 |  |
| Hazard Statements | H315-H319-H335 Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
| Precautionary Statements | P261-P280a-P305+P351+P338-P304+P340-P405-P501a Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |
