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三氟甲烷磺酸

Trifluoromethanesulfonic Acid
产品编号:3061586
规格:98+%
CAS NO:1493-13-6
包装规格:10g,50g,250g
产品类别:进口试剂
品牌:Alfa Aesar
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
306158610g417
306158650g1310
3061586250g5720
产品别名

1493-13-6

三氟甲烷磺酸

Trifluoromethanesulfonic Acid

Triflic Acid

基本信息
应用
Trifluoromethanesulfonic acid acts as a catalyst for esterification reactions and an acidic titrant in nonaqueous acid-base titration. It is useful in protonations due to the presence of conjugate base triflate is non nucleophilic. It serves as a deglycosylation agent for glycoproteins. In addition, it is a precursor and a catalyst in organic chemistry. It reacts with acyl halides to prepare mixed triflate anhydrides, which are strong acylating agents used in Friedel-Crafts reactions. It acts as a key starting material for the preparation of ethers and olefins by reacting with alcohols as well as to prepare trifluoromethanesulfonic anhydride by dehydration reaction.
备注
Hygroscopic. Incompatible with strong oxidizing agents, strong bases, water and metals.
MDL
MFCD00007514
EINECS
216-087-5
分子式
CHF3O3S
分子量
150.07
熔点
-40°
沸点
161-162°
密度
1.708
折射率
1.3270
灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.
形态
Liquid
溶解性
Miscible with water, dimethyl sulfoxide, dimethyl formamide and acetonitrile.
Beilstein
1812100
Merck
14,9676
包装组
II
危险类别
22-34-37-52/53
Harmful if swallowed.Causes burns.Irritating to respiratory system.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
安全信息
危险等级
8
安全等级
20-23-26-36/37/39-45-60-61
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.
RTECS
PB2771000
欧盟危险品标志
  
TSCA
GHS危害和防范说明
GHS符号
  
Hazard Statements
H302-H314-H318-H335-H402-H412
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause respiratory irritation.Harmful to aquatic life.Harmful to aquatic life with long lasting effects.
Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
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