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二氯三苯基膦[双(2-(乙硫基)乙基)胺]钌(II)

Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)
产品编号:3076110
规格:97%
CAS NO:1462397-86-9
包装规格:100 MG,500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
3076110100 MG611
3076110500 MG2470
产品别名

1462397-86-9

二氯三苯基膦[双(2-(乙硫基)乙基)胺]钌(II)

Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

Ru-SNS catalyst

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C26H34Cl2NPRuS2
Molecular weight
627.63
MDL number
MFCD26960799
PubChem Substance ID【PubChem化学物质编号】
329765759
NACRES
NA.22
General description【一般描述】
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application【应用】
Catalyst for the hydrogenation of esters to alcohols.
Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
Other Notes【其他说明】
"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."
Legal Information【法律信息】
This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
reaction suitability
core: ruthenium
reagent type: catalyst
greener alternative product characteristics【环保替代产品特性】
Catalysis
Learn more about the Principles of Green Chemistry.
mp
300-310 ℃
greener alternative category【环保替代产品分类】
Aligned
SMILES string
CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
InChI
1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
InChI key
ZQGMNGJIEYHKBR-UHFFFAOYSA-L
packaging【包装】
100, 500 mg in glass bottle
安全信息
Pictograms【象形图】
GHS06
Signal word【警示用语:】
Danger
Hazard Statements
H302 + H312 - H331
Precautionary Statements
P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
Hazard Classifications【危险分类】
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
Storage Class Code【储存分类代码】
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
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