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Garg 3,4-pyridyne precursor

产品编号:3090039
规格:97%
CAS NO:1211583-40-2
包装规格:1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
30900391 G2410
产品别名

1211583-40-2

Garg 3,4-pyridyne precursor

4-(Trimethylsilyl)pyridin-3-yl trifluoromethanesulfonate

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C9H12F3NO3SSi
Molecular weight
299.34
MDL number
MFCD18257070
PubChem Substance ID【PubChem化学物质编号】
329768499
Application【应用】
Pyridyne precursor can be activated under mild fluoride conditions; which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.
Other Notes【其他说明】
Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions
Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model
Please note that sigma-aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. sigma-aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
form【形式】
liquid
refractive index【折射率】
n/D 1.455
density
1.259 at 25 ℃
storage temp.【储存温度】
2-8℃
SMILES string
C[Si](C)(C)C1=C(OS(=O)(C(F)(F)F)=O)C=NC=C1
InChI
1S/C9H12F3NO3SSi/c1-18(2,3)8-4-5-13-6-7(8)16-17(14,15)9(10,11)12/h4-6H,1-3H3
InChI key
HJIBLRJECSPWKZ-UHFFFAOYSA-N
packaging【包装】
1 g in amber glass bottle
100 mg in amber glass bottle
Each AldrichCPR product will be packaged in one consolidated unit unless you specify multiple units at the time of order.
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
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