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三氯氧代 [(二甲基硫醚)三苯基膦氧化物] 铼 (V)

Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
产品编号:3178081
规格:97%
CAS NO:108695-90-5
包装规格:250 MG,1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
3178081250 MG705
31780811 G2440
产品别名

108695-90-5

三氯氧代 [(二甲基硫醚)三苯基膦氧化物] 铼 (V)

Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)

Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C20H21Cl3O2PReS
Molecular weight
648.98
MDL number
MFCD08276862
PubChem Substance ID【PubChem化学物质编号】
24884712
NACRES
NA.22
Application【应用】
Catalyst for:
  • Enantioselective reduction of ketones and imines
  • Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
  • Synthesis of 2-deoxy-α glycosides
  • Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
form【形式】
powder
reaction suitability
core: rhenium
reagent type: catalyst
SMILES string
CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChI key
GIBDGLAUIKUJJX-UHFFFAOYSA-K
packaging【包装】
1 g in glass bottle
250 mg in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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