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叔丁基二甲基甲硅烷基缩水甘油醚
tert-Butyldimethylsilyl glycidyl ether
产品别名
78906-15-7
叔丁基二甲基甲硅烷基缩水甘油醚
tert-Butyldimethylsilyl glycidyl ether
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C9H20O2Si |
| Molecular weight | 188.34 |
| MDL number | MFCD02683555 |
| PubChem Substance ID【PubChem化学物质编号】 | 24874536 |
| General description【一般描述】 | tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence of R-(salen)Co complex and water. |
| Application【应用】 | tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol. |
产品性质
| Assay【测定】 | 98% |
| refractive index【折射率】 | n |
| bp | 195-197 ℃ (lit.) |
| density | 0.901 g/mL at 25 ℃ (lit.) |
| SMILES string | CC(C)(C)[Si](C)(C)OCC1CO1 |
| InChI | 1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3 |
| InChI key | YANSSVVGZPNSKD-UHFFFAOYSA-N |
| packaging【包装】 | 10 g in glass bottle |
安全信息
| Storage Class Code【储存分类代码】 | 10 - Combustible liquids |
| WGK | WGK 3 |
| Flash Point(F)【闪点(F)】 | 158.0 °F - closed cup |
| Flash Point(C)【闪点(C)】 | 70 ℃ - closed cup |
| Personal Protective Equipment【个人防护装备】 | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) |
