三(三苯基膦)二氯化钌(II)

[(C₆H₅)₃P]₃RuCl₂

958.83

4935939

239-569-7

MFCD00013077

24853394

NA.22

Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl₂(PPh₃)₃] can be used as a catalyst to synthesize:

• Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp³ C-H bond activation of primary alcohols in the presence of Lewis acid.
• Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
• 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
• Vinyl chloride monomer by hydrochlorination reaction of acetylene.

RuCl₂(PPh₃)₃ can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.

100

97%

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2

WIWBLJMBLGWSIN-UHFFFAOYSA-L

1, 5, 25 g in glass bottle

13 - Non Combustible Solids

WGK 3

dust mask type N95 (US), Eyeshields, Gloves