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Yu Fluorination Ligand
产品别名
1771764-64-7
Yu Fluorination Ligand
2,5,6,8-tetramethyl-3,4-dihydro-2H-pyrano[2,3-b]quinoline
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C16H19NO |
| Molecular weight | 241.33 |
| PubChem Substance ID【PubChem化学物质编号】 | 329772697 |
| NACRES | NA.22 |
| General description【一般描述】 | Yu Fluorination Ligand is widely employed for the chemoselective functionalization of sp2- and sp3 C-H bonds. |
| Application【应用】 | The Yu Fluorination Ligand in tandem with Selectfluor(R) (Aldrich 439479) under palladium catalysis can promote direct fluorination of C(sp3)-H bonds stereoselectively. Yu and coworkers have displayed this on amino acid derivatives with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806). |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | ≥95% |
| form【形式】 | powder |
| reaction suitability | reagent type: ligand reaction type: C-H Activation |
| SMILES string | CC1=C2C(OC(C)CC2)=NC3=C1C(C)=CC(C)=C3 |
| InChI | 1S/C16H19NO/c1-9-7-10(2)15-12(4)13-6-5-11(3)18-16(13)17-14(15)8-9/h7-8,11H,5-6H2,1-4H3 |
| InChI key | LOKRNFHHPZEJLL-UHFFFAOYSA-N |
| packaging【包装】 | 250 mg in glass bottle |
安全信息
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
