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(+)-3-(三氟乙酰基)樟脑
(+)-3-(Trifluoroacetyl)camphor
产品别名
51800-98-7
(+)-3-(三氟乙酰基)樟脑
(+)-3-(Trifluoroacetyl)camphor
3-(Trifluoroacetyl)-
3-(三氟乙酰基)-
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C12H15F3O2 |
| Molecular weight | 248.24 |
| Beilstein | 6779716 |
| EC number【EC 号】 | 257-429-3 |
| MDL number | MFCD00003746 |
| PubChem Substance ID【PubChem化学物质编号】 | 24851361 |
| NACRES | NA.22 |
| Application【应用】 | (+)-3-(Trifluoroacetyl)camphor reacts with suitable chiral ketone precursors to generate chiral dioxiranes in situ, which can catalyse the direct asymmetric epoxidation of unfunctionalized olefins. |
产品性质
| Assay【测定】 | 98% |
| form【形式】 | liquid |
| optical activity【旋光性】 | [α]19/D +148°, c = 2.3 in methylene chloride |
| refractive index【折射率】 | n |
| bp | 100-101 ℃/16 mmHg (lit.) |
| density | 1.172 g/mL at 25 ℃ (lit.) |
| SMILES string | CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)F |
| InChI | 1S/C12H15F3O2/c1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1 |
| InChI key | ISLOIHOAZDSEAJ-XGLFCGLISA-N |
| packaging【包装】 | 1 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 10 - Combustible liquids |
| WGK | WGK 3 |
| Flash Point(F)【闪点(F)】 | 179.6 °F - closed cup |
| Flash Point(C)【闪点(C)】 | 82 ℃ - closed cup |
| Personal Protective Equipment【个人防护装备】 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
