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2:1 2,2′-联吡啶：六氟磷酸环戊二烯基(n6-萘)钌(II)
2:1 2,2′-Bipyridine:Cyclopentadienyl(n6-napthalene)ruthenium(II) hexafluorophosphate
产品别名
2:1 2,2′-联吡啶：六氟磷酸环戊二烯基(n6-萘)钌(II)
2:1 2,2′-Bipyridine:Cyclopentadienyl(n6-napthalene)ruthenium(II) hexafluorophosphate
Herzon Hydration Catalyst
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C25H21N2Ru · PF6 |
| Molecular weight | 595.48 |
| PubChem Substance ID【PubChem化学物质编号】 | 329817529 |
| Application【应用】 | Ready mixed, single catalyst system developed by the Herzon Group for terminal alkyne functionalization. Used recently by that group to affect the anti-Markovnikov reductive hydration alkynes. Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes |
| Other Notes【其他说明】 | Please note that sigma-aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. sigma-aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final. NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE. |
产品性质
| Quality Level【质量水平】 | 100 |
| SMILES string | F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=CC=CC=N1.C3(C4=NC=CC=C4)=CC=CC=N3.[C]56[C][C][C][C][C]5C=CC=C6.[Ru+].[C]7[C][C][C][C]7 |
| InChI | 1S/2C10H8N2.C10H8.C5H5.F6P.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2-6-10-8-4-3-7-9(10)5-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-8H;1-8H;1-5H;;/q;;;;-1;+1 |
| InChI key | YFGQTOCRCOVSBH-UHFFFAOYSA-N |
安全信息
| Pictograms【象形图】 | GHS05,GHS07 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H302 - H318 |
| Precautionary Statements | P280 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 4 Oral - Eye Dam. 1 |
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
