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[3-(乙氧羰基)丙基]三苯基溴化膦

[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide
产品编号:3291880
规格:97%
CAS NO:50479-11-3
包装规格:25 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
329188025 G1550
产品别名

50479-11-3

[3-(乙氧羰基)丙基]三苯基溴化膦

[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide

NSC 269919

结构式
基本信息
Linear Formula【线性分子式】
C2H5O2C(CH2)3P(C6H5)3Br
Molecular weight
457.34
MDL number
MFCD00274610
PubChem Substance ID【PubChem化学物质编号】
24861713
NACRES
NA.22
Application【应用】
Reactant for:
  • Asymmetric synthesis of antihypercholesterolemic ezetimibe via Wittig reaction
  • Wittig reactions

[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide can be used:
  • As a reactant in the synthesis of spirocyclic GPR119 agonists.
  • In the synthesis of cyclic acetal intermediate of azadirachtin, a terpenoid found in the neem tree Azadirachta indica.
  • To prepare a catechin metabolite named 5-(3,4,5-trihydroxyphenyl)valeric acid.

产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
reaction suitability
reaction type: C-C Bond Formation
mp
165-167 ℃ (lit.)
SMILES string
[Br-].CCOC(=O)CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C24H26O2P.BrH/c1-2-26-24(25)19-12-20-27(21-13-6-3-7-14-21,22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h3-11,13-18H,2,12,19-20H2,1H3;1H/q+1;/p-1
InChI key
JPZMNVPVVYVXAD-UHFFFAOYSA-M
packaging【包装】
25 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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