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(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline
产品别名
149341-33-3
(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline
(S)-QUINAP
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C31H22NP |
| Molecular weight | 439.49 |
| Beilstein | 6664856 |
| MDL number | MFCD01073773 |
| PubChem Substance ID【PubChem化学物质编号】 | 329765641 |
| NACRES | NA.22 |
| General description【一般描述】 | (S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions. |
| Application【应用】 | (S)-QUINAP can be used as a ligand:
[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes. |
产品性质
| Assay【测定】 | ≥95.0% (qNMR) |
| optical purity【光学纯度】 | enantiomeric excess: ≥98.0% |
| storage temp.【储存温度】 | 2-8℃ |
| InChI | 1S/C31H22NP/c1-3-13-25(14-4-1)33(26-15-5-2-6-16-26)29-20-19-23-11-7-9-17-27(23)30(29)31-28-18-10-8-12-24(28)21-22-32-31/h1-22H |
| InChI key | YMJAIEYASUCCMJ-UHFFFAOYSA-N |
安全信息
| Pictograms【象形图】 | GHS07,GHS07 |
| Signal word【警示用语：】 | Warning-Warning |
| Hazard Statements | H302 - H315 - H319 - H335 - H302 - H315 - H319 - H335 |
| Precautionary Statements | P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
