(叔丁氧基羰基甲基)溴化三苯基磷

(CH₃)₃CO₂CCH₂P(C₆H₅)₃Br

459.36

MFCD00075527

24862950

NA.22

Reactant for:

• Rhodium-catalyzed asymmetric hydrogenation reactions
• Wittig reaction
• Wittig methylenation
• Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
• Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
• Wittig chain extension reactions

98%

reaction type: C-C Bond Formation

178 ℃ (dec.) (lit.)

[Br-].CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3

1S/C24H26O2P.BrH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1

ZGLFRTJDWWKIAK-UHFFFAOYSA-M

10, 50 g in poly bottle

GHS07

Warning

H315 - H319 - H335

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Respiratory system

11 - Combustible Solids

WGK 3

dust mask type N95 (US), Eyeshields, Gloves