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双(环辛二烯)四(3,5-双(三氟甲基)苯基)硼酸铱(I)

Chiralyst P1271
产品编号:3414958
规格:Umicore
CAS NO:666826-16-0
包装规格:500 MG,2 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3414958500 MG1660
34149582 G5550
产品别名

666826-16-0

双(环辛二烯)四(3,5-双(三氟甲基)苯基)硼酸铱(I)

Chiralyst P1271

Bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Bis(cyclooctadiene)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

结构式
基本信息
Linear Formula【线性分子式】
(Ir(C8H12)2)+ (B(C8H3F6)4)-
Molecular weight
1271.79
MDL number
MFCD10567389
PubChem Substance ID【PubChem化学物质编号】
329761619
NACRES
NA.22
Application【应用】
Catalyst for:
  • Asymmetric hydrogenation reactions
  • Directed cyclodehydration reaction
  • Direct prenylation via C-H oxidative addition-allene insertion
  • Double intramolecular hydroalkoxylation
  • Intramolecular hydroamination reactions
  • Directed C-H bond cleavage
  • Imine vinylation reactions

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Legal Information【法律信息】
Product of Umicore

Additional information available at www.pmc.umicore.com
产品性质
Quality Level【质量水平】
100
reaction suitability
core: iridium
reagent type: catalyst
SMILES string
[Ir+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F
InChI
1S/C32H12BF24.2C8H12.Ir/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;2*1-2-4-6-8-7-5-3-1;/h1-12H;2*1-2,7-8H,3-6H2;/q-1;;;+1/b;2*2-1-,8-7-;
InChI key
YQXKTVMJDKWGHI-AUUWQFPRSA-N
packaging【包装】
2 g in glass bottle
500 mg in glass bottle
安全信息
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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