氯双环戊基膦

C₁₀H₁₈ClP

204.68

MFCD06798131

24883629

NA.22

Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf

Chlorodicyclopentylphosphine may be used to prepare:

• Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol]
• (S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone
• L^cPeNiCl, a precursor for preparing L^cPeNiH, which is an efficient catalyst for the reduction of CO₂[cPe=cyclopentyl]

100

97%

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

1.069 g/mL at 25 ℃ (lit.)

phosphine

ClP(C1CCCC1)C2CCCC2

1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2

QTYRJBRBODDGCQ-UHFFFAOYSA-N

5 g in glass bottle

GHS05

Danger

H314

P280 - P305 + P351 + P338 - P310

Skin Corr. 1B

EUH014

8A - Combustible, corrosive hazardous materials

WGK 3

230.0 °F - closed cup

> 110 ℃ - closed cup

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter