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(1S)-(-)-2,10-樟脑磺内酰胺
(1S)-(-)-2,10-Camphorsultam
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3430549 | 5 G | 1210 |
产品别名
94594-90-8
(1S)-(-)-2,10-樟脑磺内酰胺
(1S)-(-)-2,10-Camphorsultam
[3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide
(-)-exo-10,2-Bornanesultam
(1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-Dioxide
(-)-10,2-Camphorsultam
(-)-10,2-樟脑磺内酰胺
[3aS-(3aα,6α,7aβ)]-六氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物
(-)-exo-10,2-莰烷磺内酰胺
(1S,5R)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸烷-3,3-二氧化物
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C10H17NO2S |
| Molecular weight | 215.31 |
| Beilstein | 83811 |
| MDL number | MFCD00066271 |
| PubChem Substance ID【PubChem化学物质编号】 | 24857980 |
| NACRES | NA.22 |
| General description【一般描述】 | (1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. |
| Application【应用】 | (1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. |
产品性质
| Quality Level【质量水平】 | 200 |
| Assay【测定】 | 98% |
| optical activity【旋光性】 | [α]19/D −32°, c = 5 in chloroform |
| mp | 181-183 ℃ (lit.) |
| SMILES string | [H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C |
| InChI | 1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1 |
| InChI key | DPJYJNYYDJOJNO-NQMVMOMDSA-N |
| packaging【包装】 | 5 g in glass bottle |
安全信息
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Gloves |
