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(1S,4S,8S)-5-苄基-8-甲氧基-1,8-二甲基-2-(2′-甲基丙基)-双环[2.2.2]辛-2,5-二烯
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene
产品别名
862499-50-1
(1S,4S,8S)-5-苄基-8-甲氧基-1,8-二甲基-2-(2′-甲基丙基)-双环[2.2.2]辛-2,5-二烯
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene
(1S,4S,8S)--5-Benzyl-8-methoxy-1,8-dimethyl-2-(2′-methylpropyl)-bicyclo[2.2.2]octa-2,5-diene
(1S,4S,8S) Carreira DOLEFIN Ligand
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethyl-2-bicyclo[2.2.2]octa-2,5-diene
(1S,4S,8S)-5-苄基-2-异丁基-8-甲氧基-1,8-二甲基-2-双环[2.2.2]辛-2,5-二烯
(1S,4S,8S) Carreira DOLEFIN 配体
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C22H30O |
| Molecular weight | 310.47 |
| MDL number | MFCD09265063 |
| PubChem Substance ID【PubChem化学物质编号】 | 329762875 |
| General description【一般描述】 | (1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone. |
| Application【应用】 | Carreira DOLEFIN Ligands (1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene is mainly useful for the stereoselective synthesis of diarylmethine stereogenic centers. |
产品性质
| Assay【测定】 | 97% |
| form【形式】 | liquid |
| optical activity【旋光性】 | [α]/D −84±5°, c = 0.5 in chloroform |
| reaction suitability | reaction type: click chemistry |
| refractive index【折射率】 | n |
| SMILES string | CO[C@@]1(C)C[C@@]2(C)C=C(Cc3ccccc3)[C@@H]1C=C2CC(C)C |
| InChI | 1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m0/s1 |
| InChI key | ACWLDJOHMGJACE-BDTNDASRSA-N |
| packaging【包装】 | 100 mg in clear glass bottle |
安全信息
| Storage Class Code【储存分类代码】 | 12 - Non Combustible Liquids |
| WGK | WGK 3 |
