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Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
产品别名
2030437-92-2
Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
Photocatalyst
Ir Photocatalyst
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C34H16F18IrN4P |
| Molecular weight | 1045.68 |
| Application【应用】 | Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489). |
| Other Notes【其他说明】 | A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer |
产品性质
| Assay【测定】 | ≥95% |
| form【形式】 | powder or crystals |
| reaction suitability | core: iridium reagent type: catalyst reaction type: Photocatalysis |
| mp | >300 ℃ |
| photocatalyst activation | 450 nm |
安全信息
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
