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PFN-Br

产品编号:4146245
CAS NO:889672-99-5
包装规格:100 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
4146245100 MG3150
产品别名

889672-99-5

PFN-Br

Poly(9,9-bis(3’-(N,N-dimethyl)-N-ethylammoinium-propyl-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene))dibromide

OS0995

PFN-P2

结构式
基本信息
Linear Formula【线性分子式】
(C56H80N2.Br2)n
Application【应用】
PFN-Br is a solution processible, conjugated polymer electrolyte used as interficial layer in high performance organic photovoltaic cells (OPV) and organic light emitting diodes (OLED) to improve the interfacial properties.

OPV devices with PFN-Br interfacial layer showed overall enhanced short-circuit current density, open-circuit voltage, fill factor and corresponding high efficiency in the inverted OPVs. This was attributed to the good contact between ZnO electron extraction layer and the active layer, good interface adhesion between the electron extraction layer and active layer, and enhanced charge transport via suppressed bimolecular recombination.

Recent report of OPV with a record energy conversion efficiency of 17.3% also utilized PFN-Br, spin-coated on top of ZnO to improve the interfacial properties.

Tandem Cell Device performance:
ITO/ZnO/PFN-Br/PBDB-T:F-M/M-PEDOT/ZnO/PTB7- Th:O6T-4F:PC71BM/MoO3/Ag
Voc=1.642 V
Jsc=14.35 mA/cm2
FF=73.7%
PCE=17.3%

PFN-Br finds application in a wide range of areas:
  • OPV interficial layer (metalic oxide compact layer)
  • OLED electron transport layer
  • Perovskite solar cells
  • Flexible printed electronics
  • Cationic polymer electrolyte
  • Anion exchange material
  • Light emitting electrochemical cells
Other Notes【其他说明】
Recommend to use 0.2 mg/ml concentration for electron-transport interfacial layer in OPV.
产品性质
form【形式】
solid
mol wt【分子量】
Mw 30,000-50,000 by GPC
color【颜色】
beige to yellow
solubility【溶解性】
DMF: soluble
DMSO: soluble
alcohol: soluble
chloroform: insoluble
water: soluble
PDI
2‑3.2
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
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