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PhPAd-DalPhos Ni(o-tolyl)Cl
产品别名
2290490-29-6
PhPAd-DalPhos Ni(o-tolyl)Cl
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C35H37ClNiO3P2 |
| Molecular weight | 661.76 |
| Application【应用】 | PhPAd-DalPhos Ni(o-tolyl)Cl is an air stable precatalyst developed in the Stradiotto lab used for coupling of bulky primary amines with arenes. |
| Other Notes【其他说明】 | Technology Spotlight: DalPhos ligands PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines |
产品性质
| Assay【测定】 | ≥95% |
| form【形式】 | powder |
| mp | 235-248 ℃ |
| SMILES string | Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C |
安全信息
| Pictograms【象形图】 | GHS07,GHS08,GHS09 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H302 + H332 - H334 - H341 - H351 - H361f - H372 - H410 |
| Precautionary Statements | P202 - P260 - P264 - P273 - P301 + P312 - P308 + P313 |
| Hazard Classifications【危险分类】 | Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1 |
| Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| WGK | WGK 3 |
