氯化锡(II)

SnCl₂

189.62

MFCD00011241

free-flowing

SnCl₂ dihydrate reacts with acetic anhydride to yield anhydrous SnCl₂. SnCl₂ exhibits reducing properties in acidic media. SnCl₂ shows superior catalytic action in its molten state. It is a promising raw material for the chemical vapour deposition (CVD) of semiconducting layers. SnCl₂ participates in the reduction of aromatic nitro compounds, nitriles, cyanosilyl ethers and organic azides.

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Tin(II) chloride (SnCl₂) has been used as a starting material to evaluate the thermal behavior of SnCl₂ on heating at the rate of 5℃min^-1 in air. The product undergoes phase transformation on heating at rate of 5℃ min^-1 in air, it involves an incomplete evaporation followed by oxidation forming SnO₂ nanoparticles. SnCl₂ has also been used for the fabrication of Sn-containing carbon nano-structures.
Tin(II) chloride may be used:

• To catalyze the addition of diazo sulfones, diazo phosphine oxides and diazo phosphonates to aldehydes to form β-keto sulfones, β-keto phosphine oxides and β-keto phosphonates, respectively.
• Along with trityl chloride, to catalyze the aldol reaction of silyl enol ethers with acetals or aldehydes and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones.
• As a promoter in the allylic amination of allylic alcohols with amines in the presence of palladium catalyst.

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anhydrous
reagent grade

Redi-Dri^™

98%

652 ℃ (lit.)

246 ℃ (lit.)

Cl[SnH2]Cl

1S/2ClH.Sn/h2*1H;/q;;+2/p-2

AXZWODMDQAVCJE-UHFFFAOYSA-L

GHS05,GHS07,GHS08

Danger

H290 - H302 + H332 - H314 - H317 - H335 - H373 - H412

P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 + P310

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Cardio-vascular system, Respiratory system

8B - Non-combustible, corrosive hazardous materials

WGK 3